44-48

STUDY OF CADMIUM OCTA(4-METHOXYPHENYL)PORPHYRINATE IN REACTION OF METAL EXCHANGE WITH TIN CHLORIDE IN DMF

Metal-exchange reaction for complexes with macrocyclic ligands refers to a special type of complex coordination interactions. The reaction of metal exchange has founded wide application for the synthesis of complexes of natural and synthetic porphyrins. In the general form, the metal-exchange reaction may be written as follows:
MР + M/Xn(Solv)m-n M/Р + MXn(Solv)m-n

2016, Т. 59, № 6, Стр. 44-48