Movsum-zade N.Ch.

NITRILE COMPLEXES AS EFFECTIVE ANTIMICROBIAL ADDITIVES

Antimicrobial properties of nitrile complexes of transition metal salts were studied in-cluding the investigation of their activity in surfactants and mineral oil environments. Exper-iments of the polymeric complexes preparation by in-situ copolymerization of the nitrile pol-ymers in the presence of transition metal salts and reactions of transition metal salts added to the ready polymers were performed. The dependence of the polymer complexes forming par-ticularities on central metal atoms nature was determined.

Key words: transition metal salts complexes, polyacrylonitrile, poly(styrene-acrylonitrile), poly(acryl-onitrile-butadiene-styrene), ab initio calculations, thermodynamic parameters

REFERENCES
1. Gabrielyants G.А. Geology of the oil and gas fields. М.: Nedra. 2003. 285 p. (in Russian).
2. Safiullina I.I., Dubinina A.E., Babaev E.R., Movsumzade E.M. // Neftepererabotka I neftekhimiya. Scientific and technical achievements and advanced experience. 2015. V. 11.

2016, Т. 59, № 5, Стр. 81-89

THEORETICAL INVESTIGATION OF THERMODYNAMIC PARAMETERS OF TRANSITION METAL SALTS COMPLEXATION WITH ACRYLONITRILE-STYRENE ...

THEORETICAL INVESTIGATION OF THERMODYNAMIC PARAMETERS OF TRANSITION METAL SALTS COMPLEXATION WITH ACRYLONITRILE-STYRENE COPOLYMER

Thermodynamic parameters of formation reactions of polymer complexes of transition metals (ZnCl2, CuCl2, NiCl2, СоС12) were obtained using the PBE96/SVP computational level. Chemical processes taking place during both direct copolymerizations in the presence of transition metal salts and at introduction of transition metal salts at final step of polymerization were considered. The success of formation reaction of polymer complexes was theoretically based with the radical polymerization into solutions of transition metal salts in the presence of zink chloride only.

Key words: complexes, transition metal salts, poly(styrene-acrylonitrile), ab initio calculations

2016, Т. 59, № 4, Стр. 14-21
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