Bakhmudkadieva Z.N.

KINETICS OF CHARGING INTERFACE OF BLOCKED ELECTRODE-SOLID ELECTROLYTE IN GALVANODYNAMIC AND POTENTIODYNAMIC MODES...

KINETICS OF CHARGING INTERFACE OF BLOCKED ELECTRODE-SOLID ELECTROLYTE
IN GALVANODYNAMIC AND POTENTIODYNAMIC MODES. CASE OF DELAYED DIFFUSION AND ADSORPTION-DESORBTION OF TWO PARTICLE OF DIFFERENT KIND

The kinetics of charging the blocked (inert) electrode/ solid electrolyte interface was studied by operational impedance method in the galvanodynamic and potentiodynamic modes. For calculations the equivalent electrical scheme of Jacobsen and West method was used which is suitable in the case of long time of charging. The participation of two different electrochemi-cally active particles in a process of delayed diffusion and adsorption-desorption was taken into account.

Key words: operational impedance, solid electrolyte, equivalent electrical scheme

2016, Т. 59, № 2, Стр. 41-45

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