RESEARCH OF INFLUENCE OF CROSS-LINKING AGENTS ON CHARACTERISTICS OF SPATIAL GRID AND PROPERTIES OF URETHANE POLYMER

Results of study of influence of amount of functional groups of glycidyl ethers on charac-teristics of the spatial grid of crosslinked polyurethane polymer are presented. Parameters of a three-dimensional spatial grid of investigated samples of polymeric films and their physical and mechanical properties were determined by a method of equilibrium swelling in organic solvents.

Key words: polyurethane dispersion, crosslinking agent, polymeric film, crosslinking degree

REFERENCES
1. Grablowitz H.G. Pat. 2013/051142 EР., appl. number: PCT/EP2013/051142; filed 25.01.2012; publ. 01.08.2013.
2. She Y., Zhang H., Song S., Lang Q., Pu J. // BioResources. 2013. V. 8. N 2. Р. 2594-2604.
3. Athawale V.D., Kulkarni M.A. // J. Coat. Tech. & Res. 2010. V. 7. I. 2. Р. 189-199.
4. Technology for Waterborne Coatings. / Ed. J.E. Glass. Washington, DC: American Chemical Society. 1997. Р. 164–182.
5. Pinter W.M. Pat. 2006/1618158 B1 EP., appl. number: 04760537.3; filed 13.04.2004; publ. 02.08.2006. Bull. 2006/31.
6. Glubish P.A. Application of polymers of acrylic acids and its derivatives in textile and light industry. M.: Legkaya industriya. 1975. 58 р. (in Russian).
7. Wu S., Soucek M.D. // Polymer. 2000. V. 41. I. 6. Р. 2017-2028.
8. Nanomaterials for the Life Science. V. 5: Nanostructured Thin Films and Surfaces. / Editor: Challa S.S.R. Kumar. Weinheim: WILEY-VCH Verlag GmbH & Co. 2010. 431 p.
9. Brown W.T. Pat. 1999/5936043 A U.S., appl. number: 08/756,208; filed 25.11.1996; publ. 10.08.1999.
10. Tillet G., Boutevin B., Ameduri B. // Prog. Polym. Sci. 2011. V. 36. I. 2. Р. 191-217.
11. Wen X., Mi R., Huang Y., Cheng J., Pi P., Yang Z. // J. Coat. Tech. & Res. 2010. V. 7. I. 3. P. 373-381.
12. Blank W.J., He Z.A., Picci M. // J. Coat. Tech. & Res. 2002. V. 74. I. 926. P. 33-41.
13. Smit M.A., Rosbuk H. // Proceedingd of Int. Conf. on Caoutchouc and Rubber. M.: 1984. Р. 51 (in Russian).
14. Wicks Z.W., Jones F.N., Pappas S.P., Wicks D.A. Organic Coatings: Science and Technology. New York: John Wiley & Sons. 2007. 746 p.
15. Avvakumova N.I., Budarina L.A., Divgun S.M., Zaikin A.E., Kuznetsov E.V., Kurenkov V.F. Workshop on physics and chemistry of polymers. M.: Khimiya. 1990. 304 р. (in Russian).
16. Thomas V., Jayabalan M. // J. Biomed. Mater. Res. A. 2009. V. 89A. I. 1. Р. 192–205.
17. Spirkova E., Poreba R., Pavlicevic J., Kobera L., Baldrian J., Pekarek M. // J. Appl. Polym. Sci. 2012. V. 126. I. 3.
P. 1016-1030.
18. Stachelek S.J., Alferiev I., Choi H., Kronsteiner A., Uttaya-rat P., Gooch K.J., Composto R.J., Chen I.W., Hebbel R.P., Levy R.J. // J. Biomed. Mater. Res. A. 2005. V. 72. I. 2. P. 200-212.
19. Hercule K.M. // IJC. 2011. V. 3. N 2. Р. 88-96.

2016, Т. 59, № 7, Стр. 86-91

Purchase

You will get the pdf-copy of your article by e-mail