OBTAINING AND PROPERTIES OF COMBINED POLYMERIC MATERIALS BASED ON THE 3,7,13,17-TETRAMETHYL-2,8,12,18-TETRAETHYL-5,15-BIS...

DOI: 
10.6060/tcct.20165911.5445

Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol. 2016. V. 59. N 11. P. 84-91

OBTAINING AND PROPERTIES OF COMBINED POLYMERIC MATERIALS BASED
ON THE 3,7,13,17-TETRAMETHYL-2,8,12,18-TETRAETHYL-5,15-BIS(4-NITROPHENYL)-PORPHYRIN AND ITS COPPER COMPLEX

The experimental results showing a possibility of obtaining the combined materials on the basis of polymers with chemically activated surface and 3,7,13,17-tetramethyl-2,8,12,18-tetraethyl-5,15-bis(4-nitrophenyl)porphyrine and its copper complex are presented. The chemical activation of polymers was shown to result in a change in topography and chemical structure of a near-surface layer. By means of the new functional groups formed on a sur-face of polymeric matrixes the immobilization of 3,7,13,17-tetramethyl-2,8,12,18-tetraethyl-5,15-bis(4-nitrophenyl)-porphyrine and its copper complex was carried out, and the number of the immobilized compounds was determined. It is shown that conditions of preliminary ac-tivation of polymeric matrixes, and conditions of immobilized porphyrine and its copper complex strongly affect efficiency of their binding with a polymeric surface. Research of an-ti-microbe activity of the modified materials in relation to gram-negative and gram-positive microorganisms was conducted. As the results of the conducted microbiological research it was established that the received materials possess the expressed anti-microbe activity. And, the samples modified by a copper complex show twice greater bactericidal activity than mod-ified by ligands.

Key words: composite (combined) materials, polymers, chemical activation, porphyrines, biolog-ically active materials

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2016, Т. 59, № 11, Стр. 84-91

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