Ishmuratov G.Yu.

OZONOLYTIC TRANSFORMATIONS OF (R)-4-MENTHENE-3-ONE AND ITS DERIVATIVES IN DIRECTION TO LOW MOLECULAR WEIGHT BIOREGULATORS

The author’s data on ozonolytic decyclization (ring opening) of (R)-4- menthene-3-one and its alkylated analogues and application of non-peroxide ozonolysis products in the synthesis of optically active low molecular weight bioregulators including the insects phero-mones and juvenoids were generalized. The results of comparative reactivity of the men-tioned above mono-terpenoid in the set of α, β-unsaturated cyclic enones were represented.

Key words: (R)-4-menthene-3-on, ozonolysis, reactivity, pheromones juvenoids, directed syn-thesis

2016, Т. 59, № 3, Стр. 3-17
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