Koltsov N.I.

METHOD FOR DETERMINING QUASI INVARIANTS IN KINETICS OF CHEMICAL REACTIONS

A method was developed for determining the approximate kinetic relations (quasi-invariants), which connect equilibrium constants of multi- step reactions with reagent concen-trations measured in several non-stationary experiments (multi-experiments). With this meth-od use the quasi-invariants were defined for the oxidation reaction of carbon monoxide pro-ceeding through different mechanisms.

Key words: chemical reactions, step schemes, conservation laws, quasi-invariants, multi-experiments, stratification rule, equilibrium constants

REFERENCES
1. Korzukhin M.D. // Zhurn. Fizich. Khim. 1972. V. 46. N 7. P. 1845 (in Russian).
2. Alekseev B.V., Koltsov N.I., Fedotov V.Kh. // Zhurn. Fizich. Khim. 1992. V. 66. N 12. P. 3219 (in Russian).
3. Koltsov N.I., Alekseev B.V., Fedotov V.Kh. // Zhurn. Fizich. Khim. 1988. V. 2. N 11. P. 3069 (in Russian).
4. Yablonsky G.S., Constales D., Marin G.B. // Chem. Eng. Sci. 2011. V. 66. P. 111.

2016, Т. 59, № 5, Стр. 72-76
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